3531

3337

كارشناسي ارشد

شيمي معدني

اصفهان: دانشگاه صنعتي اصفهان، دانشكده شيمي

1385

نه، 96، [II] ص.: مصور، جدول، نمودار

ص. ع. به فارسي و انگليسي

شيمي

ID3337

به فارسي و انگليسي: قابل رويت در نسخه ديجيتال

Abstract In the first part of this project a novel bispyridylamide ligand H2bpmb having twocoordinating domain each acting as a bidentate donor and metaphenylene bridging groups and the binuclear Co III Cu II and Ni II complexes of its deprotonated form acting asbuilding blocks for supramolecular architecture have been synthesized and characterized Thecrystal structures of these complexes have been determined by X ray crystallography Onemolecular box with two Cu II center and also two binuclear triple stranded helix complexeswith Co III and Ni II have been detected The number of solvent molecules of compoundshave been determined by thermogravimetric analysis TG and cyclice voltametry has beenused to determine the communication between two metal center and streo and electronic effectin copper and cobalt complexes In the second part of project a novel less rigid ligand H2mpb has been synthesized andcharacterized by IR Mass and 1H NMR X Ray crystallography The structural data have beenused to rationalize the splitting of the NH peack in the IR spectrum pdfMachine A pdf writer that produces quality PDF files with ease Produce quality PDF files in seconds and preserve the integrity of your original documents Compatible across nearly all Windows platforms simply open the document you want to convert click print select the Broadgun pdfMachine printer and that s it Get yours now

مهدي اميرنصر

ثريا مقدادي

ولي اله ميرخاني،امان الله امين زاده