6600

422 دكتري

دكتري

شيمي معدني

اصفهان: دانشگاه صنعتي اصفهان، دانشكده شيمي

1390

سيزده،260ص.: مصور،جدول،نمودار

ص.ع.به فارسي و انگليسي

شيمي

ID422 دكتري

به فارسي و انگليسي: قابل رويت در نسخه ديجيتالي

The Investigation of the Coordination Modes of Flexible Multidentate Ligands and the Synthesis of Cu I Halide Aggregate Synthesis and the Investigation of the Switching Capabilities of Some Ruthenium Acetylide Molecular Switches Incorporating Dithiopheneethane DTE Mahbod Morshedi Mahbod morshedi@ch iut ac ir 27 8 2012 Department of Chemistry Isfahan University of Technology Isfahan 84156 83111 Iran Degree Ph D Language Farsi Supervisors Mehdi Amirnasr and Mark G Humphrey Email Amirnasr@cc iut ac ir Abstract The first section of this thesis includes our efforts for better understanding of theconstruction of 1D Cu I halo aggregates using flexible multidentate schiff base ligands Atfirst using the very flexible starting bis amine four Schiff ligand were synthesized as listedbelow ca2dapte 2 py2dapte 7 thio2dapte 13 and 4 NO2 Ph 2dapte 15 Using these ligands and their conformational habits and coordination modes wereinvestigated resulting in the synthesis of ca2dapte Cu ca2dapte ClO4 3 Cu PPh3 I 2 ca2dapte 4 Cu PPh3 Br 2 ca2dapte 5 Cu NCS ca2dapte 6 py2dapte Cu py2dapte PF6 2 8 Ni py2dapte PF6 2 9 Co py2dapte PF6 2 10 Fe py2dapte PF6 2 11 CuI 2 py2dapte 12 thio2dapte Cu2 I 2 thio 2dapte n 14 4 NO2 Ph 2dapte Cu2 I 2 4 NO2 Ph 2dapte n 16

مهدي اميرنصر

مارك هامفري

كاظم كرمي، علي مرسلي، ولي ا... ميرخاني