8079

553 دكتري

دكتري

شيمي معدني

اصفهان: دانشگاه صنعتي اصفهان، دانشكده شيمي

1392

ده،243ص.: مصور،جدول،نمودار

ص.ع.به فارسي و انگليسي

شيمي

ID553 دكتري

به فارسي و انگليسي: قابل رويت در نسخه ديجيتالي

The Investigation of the Coordination Modes of Flexible Multidentate Ligands and the Synthesis of Cu I Halide Aggregate and Synthesis and the Investigation of amide complexes Co III Mahdieh Rasouli M Rasouli@ch iut ac ir 22 5 2013 Department of Chemistry Isfahan University of Technology Isfahan 84156 83111 Iran Degree Ph D Language Farsi Supervisor Mehdi Amirnasr Email Amirnasr@cc iut ac ir Abstract The first section of this thesis includes our efforts for better understanding of the construction of 1D Cu I halo aggregates using flexible multidentate schiff base ligands At first using the very flexible starting bis amine four Schiff ligand were synthesized as listed below phca2dapte 2 benz 2dapte 6 2 6 diCl ph 2dapte 8 4 MeO Ph 2dapte 10 4 NO2 ph 2dapte 12 and 3 NO2 ph 2dapte 14 Using these ligands and their conformational habits and coordination modes were investigated resulting in the synthesis of phca2dapte Cu phca2dapte ClO4 3 Cu PPh3 I 2 phca2dapte 4 Cu PPh3 Br 2 phca2dapte 5 benz 2dapte Cu2 I 2 benz 2dapte n 7 2 6 diCl Ph 2dapte Cu2 I 2 2 6 diCl Ph 2dapte n 9 4 MeO Ph 2dapte Cu2 I 2 4 MeO Ph 2dapte n 11 4 NO2 Ph 2dapte Cu2 Br 2 4 NO2 Ph 2dapte n 13 PDF created with pdfFactory trial version www pdffactory com

مهدي امير نصر

مهران غياثي

شهرام تنگستاني، كاظم كرمي، علي حسين كيانفر