153

200A

200A

JOURNAL OF POLYMER SCIENCE :PART A POLYMER CHEMISTRY

V.25

(1987)

P.2781-2790

Electrophilic aromactic substitution reaction,Bis-triazolinedion,Viscosity,N-methylpyrrole

The reaction of N-Methylpyrrole with 4-substituted-1,2,4-triazoline-3,5-diones (4R-TDs), i.e., MeTD (4-methylsubstituted) and phTD (4-phenyl substituted), at room temperature without use of any catalyst was investigated. The reaction is instantaneous and leads to the formation of a 2:1 adduct in high yield, with substitution occurring at the 2 and 5 positions of the pyrrole moiety via electrophilic aromatic substitution. These compounds were fully characterized by IR,**13C-NMR,*H-NMR and elemental analysis, and were used as model compounds for the polymerization reaction. The reaction of bis-triazolinediones with N-methylpyrrole was carried out in dimethylformamide at room temperature. The reactions are fast give novel polymer structures. Some structural characterization and physical properties of these new polymers are reported.

76/11

Shahsvary

GN110479