Author :
Hajipour, A. R.,Pyne, Stephen G
Title of Article :
Stereochemistry of the addition of lithiated methyl phenyl sulfoxide to nitrones
Title Of Periodical :
TETRADRON
VolumNumber :
V.48, No.42
Descriptors :
Nitrone,Chiral sulfoxides,B-hydroxy amino sulfoxide,Stereochemistry
Abstract :
The stereochemical outcome and diastereoselectivity of the reaction of lithiated methyl phenyl sulfoxide with nitrones is reported. The relative stereochemistry of the major diastereomeric products was determined by chemical correlation with the major diastereomeric products from the reaction of lithioated racemic methyl phenyl sulfoxide with imines.
