Author :
Amirnasr, M.,Hadadzadeh, H
Title of Article :
Synthesis and characterization of amine(chloro)cobaloxime derivatives. Approximate values of the angular-overlap parameter, o, for the coordinated amines
Abstract :
Four new complexes of the type [LCO**III((DO)(DOH)pn)Cl] PF***6 where (DO)(DOH) pn = N**2, N**2 - propanediylbis (2, 3-butanedione2-imine3-oxime) and L = morpholine (mrpln) (I), benzylamine (bzlan) (II), piperidine (pprdn) (III) and pyrrolidine (prldn) (IV) have been synthesized and characterized by elemental analyses and spectroscopic methods. Approximate values of the angular-overlap parameter, Q, for the coordinated amines are estimated to be: 6395, 6627, 6797, and 7076 cm**-1 for mrpln, bzlan, pprdn, and prldn, respectively.
