Author :
Amirnasr, M.,Hadadzadeh, H
Title of Article :
Synthesis and characterization of amine(chloro)cobaloxime derivatives. Approximate values of the angular-overlap parameter, o, for the coordinated amines
Abstract :
Four new complexes of the type [LCoIII ((DO)(DOH) pn) Cl) pF5 where (DO) (DOH) pn = N**2,N**2 propanediylbis (2, 3-butanedione2-imine3-oxime) and L= morpholine (mrpln) (I), benzylamine (bzlan) (II), piperdine (pprdn) (III) and pyrrolidine (prldn) (IV) have been synthesized and characterized by elemental analyses and spectroscopic methods. Approximate values of the angular-overlap parameter,o, for the coordinated amines are estimated to be:6395,6627,6797, and 7076 cm-1 for mrpln,bzlan, pprdn, and prldn,respectively.
