Author :
Morshed, M.,East, G. C.,Cimecioglu, A. L
Title of Article :
synthesis and characterization of poly(methylene Terephthalate)
Title Of Periodical :
JOURNAL OF POLYMER SCIENCEe
Abstract :
Poly(methylene terephthalate) (1GT) has been synthesixed via the reaction of cesiom or potassiom tererhthalates with dibromomethane or bromochloromethane in N-methylepyrrolidone at temperature of 80-125 C. The polymerization was relatively slower with the latter substrate,though the potassium salt was found to be equally as efficient at its cesium counterpart with dibromomethane. The polymer is insoluble in all common polyester solvents, and its high molecular weight nature (DPn =>25) was inferred from elemental analyses and its fiber forming capacity. Thermal analyses indicated that 1GT possesses poor thermal stability and decomposes rapidly during melting, the initial process being thought to be the splitting out of formaldehyde. 1GT polymers were shown to contain a homologous series of cyclic oligomers (from dimer to decamer); the two most predominant were tentatively identified as the cyclic trimer and tetramer. No change in the cyclization efficiency was observed when the potassium counterion was substituted for cesium with Br CH2 Br whereas a drastic reduction in the polymerization are the insesitivity of the reaction to the stoichiometric equivalance of the reactants and the production of reasonably high molecular weights low conversions. It is suspected that the polymerization might be occurring through an interfacial mechanism.
