• RecordNumber
    224
  • Doc. No.
    136A
  • Call. No.
    136A
  • Author

    Hajipour, A. R.,Pyne, Stephen G

  • Title of Article

    unexpected rearrangement of a B-amino sulfoxide under pummerer reaction conditions

  • Title Of Periodical
    TETRAHEDRON
  • VolumNumber
    V.50, No.47
  • Date
    (1994)
  • Page
    P.1301-13510
  • Descriptors
    Chiral sulfoxide,Bezazepine alkaloide,Pummerer rearrangment
  • Abstract
    Attempts to prepare the benzazepine ring system of the Rhoedine alkaloids using a pummerer cyclization of the B-amino sulfoxide (16) gave instead the unexpected alcohol (19). The B-amino sulfoxide (16) was prepared via a diastereoselective reduction of the B-sulfinyl enamine (8) with sodium borohydride.
  • Indexer
    1376/08
  • IndexDate
    Shahsvary
  • اطلاعات ثبت
    GN114039