RecordNumber
224
Doc. No.
136A
Call. No.
136A
Author
Hajipour, A. R.,Pyne, Stephen G
Title of Article
unexpected rearrangement of a B-amino sulfoxide under pummerer reaction conditions
Title Of Periodical
TETRAHEDRON
VolumNumber
V.50, No.47
Date
(1994)
Page
P.1301-13510
Descriptors
Chiral sulfoxide,Bezazepine alkaloide,Pummerer rearrangment
Abstract
Attempts to prepare the benzazepine ring system of the Rhoedine alkaloids using a pummerer cyclization of the B-amino sulfoxide (16) gave instead the unexpected alcohol (19). The B-amino sulfoxide (16) was prepared via a diastereoselective reduction of the B-sulfinyl enamine (8) with sodium borohydride.
Indexer
1376/08
IndexDate
Shahsvary
اطلاعات ثبت
GN114039