6732

428 دكتري

دكتري

شيمي معدني

اصفهان: دانشگاه صنعتي اصفهان، دانشكده شيمي

1390

پانزده،295ص.: مصور،جدول،نمودار

ص.ع.به فارسي و انگليسي

مهدي امير نصر

مهران غياثي

6/3/91

مسعود صلواتي نياسري، شهرام تنگستاني، علي حسين كيانفر

شيمي

ID428 دكتري

به فارسي و انگليسي: قابل رويت در نسخه ديجيتالي

Structural Effects on the Electrochemical Properties of Schiff Base and Carboxamide Complexes of d Block Transition Metals Ahmad Amiri aamiri@ch iut ac ir Date of Submission 2012 02 21 Department of Chemistry Isfahan University of Technology Isfahan 84156 83111 Iran Degree PhD Language FarsiSupervisor Mehdi Amirnasr amirnasr@cc iut ac irAbstractThe relation between structure and electrochemical reactivity underlie the participation oftransition metals in many important processes including catalysis energy conversion andbiological electron transfer In this thesis with the goal of evaluating the structural effects on the electrochemical properties offirst row d block transition metal complexes the cyclic voltammetry of a large number of schiffbase and carboxamide complexes of Cu II Ni II Co III Zn II and Cd II has been studied Ithas been found that the electron density on the metal center is not only dependent on theelectronic parameters of the donor atoms of the ligands but the structural and steric parameters alsoplay an important role on the redox properties of metal center An electrerochemical series for thestudied Schiff base and carboxamide ligands is also presented Keywords Inorganic Electrochemistry Cyclic Voltammetry Redox Properties CoordinationChemistry Structural Parameters

مهدي امير نصر

مهران غياثي

مسعود صلواتي نياسري، شهرام تنگستاني، علي حسين كيانفر