پديد آورنده :
آذر كمان زاد، زهرا
عنوان :
سنتز، شناسايي و تعيين ساختار ليگاند نامتقارن كربو كساميدي سه دندانه با استفاده از مايع يوني تترابوتيل آمونيوم برمايد TBAB و كمپلكس هاي ﴿ Zn(II) Cu(II)’ Ni(II با ليگاند دپروتونه شده
مقطع تحصيلي :
كارشناسي ارشد
گرايش تحصيلي :
شيمي معدني
محل تحصيل :
اصفهان: دانشگاه صنعتي اصفهان، دانشكده شيمي
صفحه شمار :
يازده،127ص.: مصور،جدول،نمودار
يادداشت :
ص.ع.به فارسي و انگليسي
استاد راهنما :
مهدي اميرنصر
استاد مشاور :
ثريا مقدادي
توصيفگر ها :
كمپلكس هاي كربوكساميدي , نيكل﴿II﴾ , مس﴿II﴾ , روي ﴿II﴾
تاريخ نمايه سازي :
20/1/92
استاد داور :
علي حسين كيانفر، غلامحسين محمدنژاد
چكيده فارسي :
به فارسي و انگليسي:قابل رويت در نسخه ديجيتالي
چكيده انگليسي :
128 Synthesis Characterization and Crystal Structure determination of tridentate unsymmetric Hqpzc carboxamide ligand by TBAB ionic liquid and preparation of it s complexes with Ni II Cu II and Zn II Zahra azarkamanzad zahraazarkaman@yahoo com 2013 Department of Chemistry Isfahan University of Technology Isfahan 84156 83111 Iran Degree M Sc Language Farsi Supervisor Prof M Amirnasr Email amirnasr@cc iut ac ir Abstract Ionic liquids as new reaction media and catalysts have been experimentally and theoretically recognized and accepted They are environmentally friendly or greener alternatives to organic solvents because they have very low vapor pressure and are non explosive and thermally stable over a wide temperature range They can be employed as solvents for a number of chemical processes such as separation reactions two phase catalysis extractions and polymerizations One of the new applications of ionic liquids is in the synthesis of organic compounds including amides Carboxamide ligands have been part of the growing research in the field of coordination chemistry of transition metal complexes The solvent used in the classical method of synthesis of these compounds is pyridine a solvent which is extremely toxic We have developed a new method for the synthesis of these amides using ionic liquids as the reaction media Hqpzc 1 has been prepared under optimum conditions in high yield and short reaction time The Ni II Cu II and Zn II complexes of qpzc with the formula 2 Ni qpzc N3 3 Ni qpzc 2 H2O 4 Cu qpzc OAc H2O 5 Cu qpzc OClO3 H2O 6 Cu qpzc NCS 7 Cu qpzc N3 8 Zn qpzc OAc H2O
استاد راهنما :
مهدي اميرنصر
استاد مشاور :
ثريا مقدادي
استاد داور :
علي حسين كيانفر، غلامحسين محمدنژاد
